Triethylamine-bonded sulfonic acid {[Et3N-SO3H]Cl} as an efficient and homogeneous catalyst for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones

Authors

  • Abdolkarim Zare Department of Chemistry, Payame Noor University, PO BOX 19395-4697, Tehran, Iran
  • Ahmad Reza Moosavi-Zare Department of Chemistry, University of Sayyed Jamaloddin Asadabadi, Asadabad, 6541835583, Iran
  • Alireza Hasaninejad Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran
  • Maria Merajoddin Department of Chemistry, Payame Noor University, PO BOX 19395-4697, Tehran, Iran
  • Masoud Kazem-Rostami Young Researchers Club, Takestan Branch, Islamic Azad University, Takestan, Iran
  • Mohammad Mahdi Ahmad-Zadeh Department of Chemistry, Payame Noor University, PO BOX 19395-4697, Tehran, Iran
  • Roghayyeh Khanivar Department of Chemistry, Payame Noor University, PO BOX 19395-4697, Tehran, Iran
Abstract:

Brønsted acidic ionic liquid triethylamine-bonded sulfonic acid {[Et3N-SO3H]Cl} efficiently catalyzes the one-pot multi-component condensation of 2-naphthol with arylaldehydes and dimedone (5,5-dimethylcyclohexane-1,3-dione) under solvent-free conditions to afford 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones in high yields and relatively short reaction times.

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triethylamine-bonded sulfonic acid {[et3n-so3h]cl} as an efficient and homogeneous catalyst for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones

brønsted acidic ionic liquid triethylamine-bonded sulfonic acid {[et3n-so3h]cl} efficiently catalyzes the one-pot multi-component condensation of 2-naphthol with arylaldehydes and dimedone (5,5-dimethylcyclohexane-1,3-dione) under solvent-free conditions to afford 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones in high yields and relatively short reaction times.

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Journal title

volume 2  issue 3

pages  107- 114

publication date 2012-09-01

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